Selectivity for Synthesis
By (author) Jonathan Clayden
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Organolithiums by Jonathan Clayden
Book DescriptionThis volume, number 23 in the "Tetrahedron Organic Chemistry" series, presents organolithium chemistry from the perspective of a synthetic organic chemist, drawing from the synthetic literature to present a unified overview of how organolithiums can be used to make molecules. The development of methods for the regioselective synthesis of organolithiums has replaced their image of indiscriminate high reactivity with one of controllable and subtle selectivity. Organolithium chemistry has a central role in the selective construction of C-C bonds in both simple and complex molecules, and for example has arguably overtaken aromatic electrophilic substitution as the most powerful method for regioselective functionalisation of aromatic rings. The twin themes of reactivity and selectivity run through the book, which reviews the ways by which organolithiums may be formed and the ways in which they react. Topics include advances in directed metallation, reductive lithiation and organolithium cyclisation reactions, along with a discussion of organolithium stereochemistry and the role played by ligands such as (-)-sparteine.
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Book DetailsISBN: 9780080432625
(229mm x 152mm x 21mm)
Publisher: Elsevier Science & Technology
Publish Date: 12-Jul-2002
Country of Publication: Netherlands
Books By Author Jonathan Clayden
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Inspiring and motivating students from the moment it published, Organic Chemistry has established itself in just one edition as the students' choice of organic chemistry text. Its explanatory, mechanistic, evidence-based approach makes it perfect for fostering a true understanding of the subject.
Organolithiums, Paperback (July 2002)» View all books by Jonathan Clayden
Whilst research into organolithium compounds has been ongoing, little is known about organolithium products of ortholithiation reactions. This volume contains an up-to-date survey of organolithiums and their use in synthesis.
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