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The statistical theory of unimolecular reactions is now universally known as RRKM theory. This textbook covers the basics necessary for the understanding of RRKM theory in its original and variational, phase-space and angular momentum-conserved incarnations. After a review of the Kassel quantum model and the theory of Slater, the specific-energy RRKM rate constant k(E) is derived. The argument is then extended to the angular momentum-dependent rate constant k(E,J), to non-classical effects (tunneling and non-adiabatic transition), and the general problem of angular momentum conservation. A long chapter is devoted to the counting of quantum states. The chapter on thermal systems discusses both analytical and numerical solutions and is later extended to include the variational approach and discussion of exit channel effects. Containing many problem sets and solutions, the book is targeted at graduate and advanced undergraduate students studying chemical dynamics, chemical kinetics and theoretical chemistry.

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Book Details

ISBN: 9780521529228
ISBN-10: 0521529220
Format: Paperback
(247mm x 174mm x 19mm)
Pages: 332
Imprint: Cambridge University Press
Publisher: Cambridge University Press
Publish Date: 25-Sep-2003
Country of Publication: United Kingdom

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Author Biography - Wendell Forst

Wendell Forst is affiliated with the Laboratoire de Physicochimie Moleculaire, Universite Bordeaux I, Talence, France.

Books By Author Wendell Forst

Unimolecular Reactions by Wendell Forst

Unimolecular Reactions

Hardback, September 2003
$256.50